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Qualitative and quantitative analysis of clay soils
Šašek, Petr ; Viani, Alberto ; Mácová, Petra
Smectite-to-illite conversion is an important mineralogical reaction that occurs during the diagenesis ofargillaceous sediment. Illite–smectite clay minerals are ubiquitous in sedimentary basins and they have been linked to the maturation, migration and trapping of hydrocarbons, rock cementation, evolution of porewater chemistry during diagenesis and the development of pore pressure. But, despite the importance of these clays, their structures are controversial. By combining layers of octahedra and tetrahedra several types of layered structures may be produced, which can form various types of clay minerals in nature. Clay minerals are divided into three main groups: kaolinite, smectite and illite. The aim of the study was to qualitatively and quantitatively analyse the clay minerals in soil samples and identification of unknown mineral found by exploration works. For this purpose XRD, Raman spectroscopy and SEM were employed.
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Qualitative and quantitative analysis of clay soils
Šašek, Petr ; Viani, Alberto ; Ševčík, Radek ; Fabeš, Roman ; Řehoř, M.
Clay minerals are a group of aluminum silicates with a layered structure, which is formed by tetrahedrally and octahedrally arranged molecules with cations of potassium, magnesium, sodium and others. By combining layers of octahedra and tetrahedra several types of layered structures may be produced, which can form various types of clay minerals in nature. Clay minerals are divided into three main groups: kaolinite, smectite and illite. The aim of the study was to qualitatively and quantitatively analyse the clay minerals in soil samples; the main objective was to determine the phase transition on the boundary of smectite and illite phases. For this purpose XRD analysis with Rietveld refinement was employed.
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